soln. Continue rinsing. Light Sensitive. Fluorine is the top element in the halogen column. (USCG, 1999), Inhalation of dust causes irritation of nose and throat. It is also used in the preparation of organic perfluorocompounds and in the fluorination of aromatic compounds. Properties. Odorless yellow to gray solid. Incompatible with water, reducing agents, bases, organic materials and metal powders. Silver(II) fluoride is used as a fluorinating and oxidizing agent. Hygroscopic. Terms of Use, Keep your current shopping and add the saved Cart? 3.   |   Light sensitive. Its chemical formula is AgF 2. You can disable the usage of cookies by changing the settings of your browser. Tel: (00) 800 4566 4566 or +49 (0)721 84007 280 IF SWALLOWED: Rinse mouth. Eng. or +49 (0)721 84007 280 Reacts violently with water. Keep, Remove your current shopping cart and replace with the saved cart? Hygroscopic. Carrying out the confirmation. Silver(II) fluoride is used as a fluorinating and oxidizing agent. News 44(24):7 1956]. Wear protective gloves/protective clothing/eye protection/face protection. © Copyright 2020 Alfa Aesar, Thermo Fisher Scientific. 3, 389, 651). - No smoking. DE301240889. Moisture Sensitive. Soluble in hexane, chloroform, chlorofluorocarbon and hydrogen fluoride. EUH014-H272-H302+H312+H332-H314-H410. Hygroscopic. DE301240889. Calcium D-gluconate gel, 2.5% w/w aq. See 50 Federal Register 13456 (April 4, 1985). Biomol. Office of Response and Restoration, Purify it by washing with AcOH and dry *C6H6, then keep it in a vacuum desiccator at room temperature to remove *C6H6, and store it in opaque glass bottles. Ingestion may cause vomiting, salty taste, abdominal pain, diarrhea, convulsions, collapse, thirst, disturbed color vision, and acute toxic nephritis. Applications. silver fluoride Physical appearance: cubic crystals Empirical formula (Hill's system for organic substances): AgF Structural formula as text: AgF Molar/atomic mass: 126.87 Melting point (°C): 435 Solubility (g/100 g of solvent): water: 85.8 (0°C) water: 119.8 (10°C) water: 172 (20°C) water: 179.6 (25°C) When silver fluoride is ground with calcium hydride the mass becomes incandescent [Mellor 3:389 1946-1947]. Silver(I) fluoride is used as a fluorination and desilylation reagent in organic synthesis. IF IN EYES: Rinse cautiously with water for several minutes. Solubility. Precautionary Statements: Fax: (00) 800 4577 4577 Privacy Policy This item can also be found in the following categories: Tetra-n-butylammonium fluoride trihydrate, 98%, Aluminum slug, 6.35mm (0.25in) dia x 6.35mm (0.25in) length, 99.99% (metals basis), Magnesium slug, 6.35mm (0.25in) dia x 6.35mm (0.25in) length, 99.95% (metals basis). I agree Hazard Statements: Silver(I) fluoride is used as a fluorination and desilylation reagent in organic synthesis. Tetrahedron Lett. You can disable the usage of cookies by changing the settings of your browser. (Mellor, 1941, Vol. May intensify fire; oxidizer. The precipitates are the insoluble silver halides - silver chloride, silver bromide or silver iodide. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, Silver (metal dust and soluble compounds, as Ag), National Oceanic and Atmospheric Administration. This section provides a listing of alternate names for this chemical, Confirming the precipitate using ammonia solution. Harmful in contact with skin. Yamaguchi, K.; Xu, N.; Jin, X.; Suzuki, K.; Mizuno, N. Regioselective direct oxidative C-H cyanation of quinoline and its derivatives catalyzed by vanadium-containing heteropoly acids. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. In medical filed, it is used as topical caries in aqueous form in dentistry. 2015, 13 (29), 7928-7939. So, a fluorine ion is the smallest ion of the group. Rinse skin with water/shower. It also contains fluoride ions. National Oceanic and Atmospheric Administration. CaH2 reacts incandescently with AgF if subject to friction. Light Sensitive. Silver(I) bromide: AgBr: 5.35 x 10-13: Silver(I) carbonate: Ag 2 CO 3: 8.46 x 10-12: Silver(I) chloride: AgCl: 1.77 x 10-10: Silver(I) chromate: Ag 2 CrO 4: 1.12 x 10-12: Silver(I) cyanide: AgCN: 5.97 x 10-17: Silver(I) iodate: AgIO 3: 3.17 x 10-8: Silver(I) iodide: AgI: 8.52 x 10-17: Silver(I) oxalate: Ag 2 C 2 O 4: 5.40 x 10-12: Silver… Improved cyclization conditions to prepare 6-substituted pyrazolo[1,5-a]pyridines and pyrazolo[1,5-a]pyrazines using catalytic Ag(I) and Au(III) salts. USA.gov. Privacy Policy It is a white or gray crystalline solid. Immediately call a POISON CENTER or doctor/physician. It is also used in the preparation of organic perfluorocompounds and in the fluorination of aromatic compounds. Causes severe skin burns and eye damage. (USCG, 1999). News 44(24):7 1956]. Dimethyl sulfoxide is violently reactive with fluorinating agents such as silver fluoride [Chem. Commun. Harmful if inhaled. Keep, Remove your current shopping cart and replace with the saved cart? Soluble in HF, ammonia, CH{3}CNSoluble in water, hydrogen fluoride and methanol. Hazard Statements: Fax: (00) 800 4577 4577 (USCG, 1999). Take any precaution to avoid mixing with combustibles. Clear. Nitinol™ Nickel Titanium Shape Memory Alloys, Specpure® Inorganic Standards for Water Analysis, Specpure® Oil-Based Standards for Wear Metal Analysis, Specpure® XRF Standards for Petroleum Products, Cellular Growth & Attachment Factors - BT Products, POCO Electron Beam Crucibles & Hearth Shields (Carbon Graphite), Boron, Phosphorus, Silicon, and Sulfur Compounds, Sugars, Steroids, Amino Acids, and Nucleotides, Precious Metal Compounds - Homogeneous Catalysts. It has silver in its +2 oxidation state. Incompatible with strong acids and oxidizing agents. None of the above silver is soluble. When silver fluoride is ground with calcium hydride the mass becomes incandescent [Mellor 3:389 1946-1947]. By browsing our website without changing the browser settings you grant us permission to store that information on your device. Immediately call a POISON CENTER or doctor/physician. Moisture Sensitive. including trade names and synonyms. Boron reacts explosively when ground with SILVER FLUORIDE; silicon reacts violently [Bretherick 1979 p, 197]. Very toxic to aquatic life with long lasting effects. 2015, 51 (49), 10034-10037. Contact with eyes causes irritation. Keep away from heat/sparks/open flames/hot surfaces. Applications. Braganza, J. F.; Bernier, L.; Botrous, I.; Collins, M. R.; Li, B.; McAlpine, I.; Ninkovic, S.; Ren, S.; Sach, N.; Tran-Dube, M.; Zeng, Q.; Zheng, B. Chem. By browsing our website without changing the browser settings you grant us permission to store that information on your device. Harmful if swallowed. Silver(II) fluoride, also known as argentic fluoride, is a chemical compound. Rinse skin with water/shower. 2015, 56 (42), 5757-5760. & indicates that no RQ is assigned to this generic or broad class, although the class is a CERCLA hazardous substance. Silver fluoride is soluble, and so you don't get a precipitate. Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. Wear protective gloves/protective clothing/eye protection/face protection. It is utilized in the oxidation of xenon to xenon difluoride. Keep, Replace your shopping cart with these items? Ammonia solution is added to the precipitates. I agree Ambient temperatures. Ambient temperatures. It is employed in organofluorine chemistry for addition of fluoride across multiple bonds, especially to prepare perfluoroalkylsilver(I) by reacting with alkenes. Boron reacts explosively when ground with SILVER FLUORIDE; silicon reacts violently [Bretherick 1979 p, 197]. Eng. Remove contact lenses, if present and easy to do. It serves as an intermediate in the catalysis of gaseous reactions with fluorine by silver. Further, it is involved in the preparation of tetralkylammonium fluorides by the reaction with tetralkylammonium bromide. Solubility. Look at these elements on the periodic table. © Copyright 2020 Alfa Aesar, Thermo Fisher Scientific. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. All Rights Reserved. Fight fire remotely due to the risk of explosion.